\[
\newcommand{\ra}[1]{\kern-1.5ex\xrightarrow{\ \ #1\ \ }\phantom{}\kern-1.5ex}
\newcommand{\ras}[1]{\kern-1.5ex\xrightarrow{\ \ \smash{#1}\ \ }\phantom{}\kern-1.5ex}
\newcommand{\da}[1]{\bigg\downarrow\raise.5ex\rlap{\scriptstyle#1}}
\begin{array}{c}
0 & \ra{f_1} & A & \ra{f_2} & B & \ra{f_3} & C & \ra{f_4} & D & \ra{f_5} & 0\\
\da{g_1} & & \da{g_2} & & \da{g_3} & & \da{g_4} & & \da{g_5} & & \da{g_6}\\
0 & \ras{h_1} & 0 & \ras{h_2} & E & \ras{h_3} & F & \ras{h_4} & 0 & \ras{h_5} & 0\\
\end{array}
\]

\[
\newcommand{\ra}[1]{\kern-1.5ex\xrightarrow{\ \ #1\ \ }\phantom{}\kern-1.5ex}
\newcommand{\ras}[1]{\kern-1.5ex\xrightarrow{\ \ \smash{#1}\ \ }\phantom{}\kern-1.5ex}
\newcommand{\da}[1]{\bigg\downarrow\raise.5ex\rlap{\scriptstyle#1}}
\begin{array}{c}
0 & \ra{f_1} & A & \ra{f_2} & B & \ra{f_3} & C & \ra{f_4} & D & \ra{f_5} & 0 \\
\da{g_1} & & \da{g_2} & & \da{g_3} & & \da{g_4} & & \da{g_5} & & \da{g_6} \\
0 & \ras{h_1} & 0 & \ras{h_2} & E & \ras{h_3} & F & \ras{h_4} & 0 & \ras{h_5} & 0 \\
\end{array}
\]

References:

http://meta.math.stackexchange.com/questions/2324/how-to-draw-a-commutative-diagram